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2025-09-09

Photothermal Catalysis: The Green Chemistry Magic of Sunlight and Heat Working Together

When light energy meets heat energy, and a catalyst skillfully mediates between them, they can create remarkably efficient chemical reaction phenomena.

In the pursuit of green chemistry and sustainable energy, scientists have discovered a powerful tool ——— photothermal catalysis. This technique cleverly combines the strengths of photocatalysis and thermocatalysis, using the synergistic effects of light and heat to drive reactions that are otherwise difficult to carry out under mild conditions.

Working principle of photothermal catalysis: a synergy greater than the sum of its parts

The core of photothermal catalysis lies in the synergy between light and heat. Photocatalysis uses photon energy to excite the catalyst and generate electron–hole pairs, lowering the activation energy required for reactions; thermocatalysis provides the kinetic energy for molecular motion, accelerating reaction rates. Their combination not only greatly enhances reaction efficiency but also reduces the temperatures needed, optimizing energy utilization.

Specifically, when certain nanomaterials simultaneously absorb light and heat, multiple effects arise: localized surface plasmon resonance (LSPR) can generate hot electrons and localized heating; photothermal conversion transforms light into heat, creating high-temperature "hot spots" on the catalyst surface; and hot-electron injection supplies activation energy to reactant molecules. These effects work together to promote chemical reactions.

Technical advantages: efficient reactions under mild conditions

Photothermal catalysis offers significant advantages over conventional techniques. It can achieve reactions that normally require high temperatures at relatively lower temperatures, greatly reducing energy consumption. At the same time, this approach is particularly effective at utilizing renewable energy (solar) through full-spectrum utilization (not only UV but also visible and infrared light), maximizing solar energy conversion.

Moreover, photothermal catalysis demonstrates excellent reaction selectivity, enabling precise control of reaction pathways and reducing the formation of byproducts. This technology is applicable to a variety of reaction systems, including CO₂ reduction, volatile organic compound degradation, and water splitting for hydrogen production, offering new solutions for clean energy production and environmental remediation.

Technology enabling: precise instruments driving photothermal catalysis research

In photothermal catalysis research, advanced experimental equipment is key to obtaining reliable data. Beijing Bofeilai Technology Co., Ltd. has developed the PLR-GPTR50T gas–solid photothermal reactor specifically designed for photothermal synergistic catalytic reactions. It adopts a flattened pot-style reactor and can monitor reaction pressure and the bulk temperature of the catalyst in real time via pressure and temperature sensors.

The device integrates built-in electric heating elements with a maximum heating temperature of 300°C, and uses thermocouples and a temperature controller for feedback control, achieving a temperature control accuracy of ±0.5°C. Its high-pressure metal quick-plug design enables easy switching of sealed recirculating gas flow modes, and the powder catalyst placement platform ensures more thorough contact between gas and catalyst.

For experiments requiring precise gas ratios, Bofeilai Technology's PLD-DGCS05 multicomponent dynamic gas mixer can provide accurate gas composition control, ensuring a high degree of reproducibility in experimental conditions. These precision instruments together form a complete solution for photothermal catalysis research, providing reliable technical support for researchers.

PLR-GPTR50T

Application prospects: the future path of green chemistry

Photothermal catalysis shows broad application prospects across multiple fields. In energy, it can convert CO₂ into fuels, achieving carbon recycling; in environmental remediation, it can efficiently degrade organic pollutants; and in chemical production, it can synthesize high-value chemicals under mild conditions.

With continuous advances in nanomaterial design, reactor engineering, and process optimization, photothermal catalysis is expected to play an important role in carbon neutrality and green chemistry. The fundamental data and deep understanding obtained by researchers using precision instruments are continually driving this field forward, contributing to the construction of a sustainable future.

Photothermal catalysis not only represents an innovation in chemical synthesis methods but also embodies a deep utilization of the sun—our most abundant renewable energy source. As research progresses and technologies mature, this "light–heat synergy" green chemistry magic will play an increasingly important role in our lives and industries.

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